Aircraft measurements were used to estimate the CO2 emission rates of the city of Rome, assessed against high-resolution inventorial data. Three experimental flights were made, composed of vertical soundings to measure Planetary Boundary Layer (PBL) properties, and circular horizontal transects at various altitudes around the city area. City level emissions and associated uncertainties were computed by means of mass budgeting techniques, obtaining a positive net CO2 flux of 14.7±4.5, 2.5±1.2, and 10.3±1.2 ?mol m-2 s-1 for the three flights. Inventorial CO2 fluxes at the time of flights were computed by means of spatial and temporal disaggregation of the gross emission inventory, at 10.9±2.5, 9.6±1.3, and 17.4±9.6 ?mol m-2 s-1. The largest differences between the two dataset are associated with a greater variability of wind speed and direction in the boundary layer during measurements. Uncertainty partitioned into components related to horizontal boundary flows and top surface flow, revealed that the latter dominates total uncertainty in the presence of a wide variability of CO2 concentration in the free troposphere (up to 7 ppm), while it is a minor term with uniform tropospheric concentrations in the study area (within 2 ppm). Overall, we demonstrate how small aircraft may provide city level emission measurements that may integrate and validate emission inventories. Optimal atmospheric conditions and measurement strategies for the deployment of aircraft experimental flights are finally discussed.

The effect of the nitrification inhibitor 3,4-dimethylphyrazole phosphate (DMPP) on N-fertilized crop growth and soil N2O emissions were studied at two experimental sites in Southern Italy, characterised by a Mediterranean climate and different soil texture. The experiments were a randomized block design of two treatments: crop fertilized with NH4NO3 (considered the control treatment) or amended with DMPP plus NH4NO3 (considered the DMPP treatment). ANOVA was performed to assess differences between treatments and fertilization periods whereas simple and multiple linear regressions were performed in order to assess the effect of the soil-related in-dependent variables on soil gases emissions. Growth of potato plants fertilized with DMPP-added nitrogen was enhanced compared to control plants, whereas no benefit on maize plants grown during summer was observed. N2O emissions measured from soil to potato after the first fertilization with DMPP-added nitrogen was reduced during winter, but was higher than control after the second fertilizer application in spring, leading to comparable N2O emission factors (EF1) between treatments. In maize N2O emissions and EF1 were lower for DMPP compared to control treatment. The effectiveness of reduction in soil N2O emission was influenced by soil temperature and water-filled pore space (WFPS) in both experimental sites. However, the overall effect of WFPS was contrasting as N2O emissions were decreased in potato and enhanced in maize.

Soil N2O emissions were monitored throughout a 3-year crop rotation including maize, fennel and a ryegrass-clover. sward, at Borgo Cioffi NitroEurope site. N2O emission rates were highly variable in time and space and controlled by soil nitrogen and soil water content. The N2O effluxes were low for most of the monitored period. The highest N2O emissions were recorded throughout the 2007 maize cropping season, ranged from 15.2 to 196.2 mug m-2 h-1 whereas the lowest ones ranged from -5 to 10 mug m-2 h-1 during the 2007 2008 ryegrass-clover winter crop. For the maize crops, N2O peaks were detected after fertilization but with a delay of some weeks from applications, probably due to the presence of DMPP nitrification inhibitor in the applied fertilizer. A properly designed ANOVA model was developed to explain the influence of the main chemical-physical factors. This model also allowed the quantification of the delay time in peak emissions following fertilization, which resulted variable over the years and ranged between 2 and 21 days. A dependence of emissions from soil temperature and moisture was found, with significant interactions in some instances. Calculated Emission Factors (maize 2007: 0.48%; ryegrass-clover sward 2007 2008: 0.05%; maize 2008: 0.14%; fennel: 0.28% 2008 2009; maize 2009: .015%) resulted well below the values reported in the literature and the 1% reference value indicated by IPCC, probably due to a suboptimal water regime inducing low Water Filled Pore Space (WFPS) values.

Quantifying trace gas emissions and the influence of surface exchange processes on the atmosphere is a necessary step towards the control of global greenhouse gas emissions and reliability of air quality models. This paper proposes a procedure based on the mass balance method and implemented on highly resolved aircraft data. It allows one to estimate surface exchanges on areas of several km2 and heterogeneous features exploiting the characteristics of convective boundary layer during steady state conditions that permit the estimation of emission/absorption terms as functions of advective fluxes only. A nonparametric approach is adopted and the fluxes on the surface of a virtual box surrounding the area of interest are reconstructed on the basis of scalar densities and wind vectors using Shepard functions. Two different techniques are also proposed to face lack of data on the top surface of the box. The method has been applied to experimental data coming from measurement campaigns on two different sites. It provides realistic estimates of the CO2 emission/absorption in the considered areas that are in good agreement with CO2 fluxes evaluated by Airborne Eddy Covariance and confirm the suitability of the proposed approach for the assessment of turbulent exchange of trace gases by composite landscapes. Uncertainties on the estimated emissions due to both propagation of the experimental error and interpolation have been quantified by bootstrap analysis as 6%.

Quantifying trace gas emissions and the influence of surface exchange processes on the atmosphere is a necessary step towards the control of global greenhouse gas emissions. Also air quality models require highly resolved emission data. This paper propose a procedure based on the mass balance method and implemented on highly resolved aircraft data, which allows us to estimate surface exchanges on areas of several km 2 and heterogeneous surface features. We adopt a nonparametric approach and reconstruct the fluxes on the surface of a virtual box surrounding the area of interest using Shepard functions. Two different techniques are also proposed to face lack of data on the top surface of the box. The method is applied to the experimental data from a measurement campaign in Eboli to obtain an evaluation of the CO2 emission/absorption in the area.

Uno degli interventi proposti dal protocollo di Kyoto per la stabilizzazione delle concentrazionidi gas serra si riferisce alla necessità di determinare la localizzazione delle sorgenti e delle fonti ditali gas. Il metodo del bilancio di massa, implementato a partire da misure rilevate da piattaforma aerea,presenta la potenzialità di poter quantificare gli scambi gassosi superficiali su aree di diversi chilometriquadrati, permettendo una stima anche in condizioni di eterogeneità superficiale, contrariamente ai metoditradizionali. In questo studio il metodo è stato applicato ad un sito nei pressi di Forlì utilizzando dati telerilevatiad alta frequenza nello strato limite planetario. La scarsa risoluzione verticale ottenuta in fase dirilevamento dati è stata risolta attraverso un metodo di regressione non parametrico. I campi di concentrazionedel gas e del vento in corrispondenza dell'altezza dello strato limite planetario sono determinaticon un modello additivo non parametrico. Risulta che la superficie del territorio esaminato emette un flussodi anidride carbonica di 13±0.3 ?moli/m2/s, a causa della presenza di un centro industriale all'internodell'area esaminata.