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2010 Contributo in Atti di convegno metadata only access

Approach to iron corrosion via the numerical simulation of a galvanic cell

Colicchio G ; Mansutti D ; Santarelli ML

A mathematical model of the galvanic iron corrosion is, here, presented. The iron(III)-hydroxide formation is considered together with the redox reaction. The PDE system, assembled on the basis of the fundamental holding electro-chemistry laws, is numerically solved by a locally refined FD method. For verification purpose we have assembled an experimental galvanic cell; in the present work, we report two tests cases, with acidic and neutral electrolitical solution, where the computed electric potential compares well with the measured experimental one

Iron redox reaction kinetics PDE numerical simulation
2010 Articolo in rivista metadata only access

Approach to iron corrosion via the numerical simulation of a galvanic cell

G Colicchio ; D Mansutti ; M L Santarelli

A mathematical model of the galvanic iron corrosion is, here, presented. The iron(III)-hydroxide formation is considered together with the redox reaction. The PDE system, assembled on the basis of the fundamental holding electro-chemistry laws, is numerically solved by a locally refined FD method. For verification purpose we have assembled an experimental galvanic cell; in the present work, we report two tests cases, with acidic and neutral electrolitical solution, where the computed electric potential compares well with the measured experimental one

Iron redox reaction kinetics PDE numerical simulation
2009 Articolo in rivista metadata only access

A numerical model of an experiment of iron corrosion

D Mansutti ; G Colicchio ; ML Santarelli

An improvement of a mathematical model of the galvanic iron corrosion, previously presented by one of the authors, is here proposed. The iron(III)-hydroxide formation is, now, considered in addition to the redox reaction. The PDE system, assembled on the basis of the fundamental holding electro-chemistry laws, is numerically solved by a locally refined FD method. For verification purpose we have assembled an experimental galvanic cell; in the present work, we report two tests cases, with acidic and neutral electrolitical solution, where the computed electric potential compares well with the measured experimental one.

convection-diffusion equations electrochemistry iron