In this contribution, we provide an overview of the EMM (Earth and Mars Research Network) research infrastructure, outlining its main components and the potential scientific products that can be derived through its use. The presentation delves into selected aspects in greater detail, particularly where they resonate with the multiple scientific and technological challenges associated with the FORUM mission.

MIPAS is a Fourier Transform spectrometer that measured the atmospheric limb emission spectra in the middle infrared on board the ENVISAT satellite. These measurements allowed the global monitoring of the three-dimensional (latitude, longitude and altitude) distribution of temperature and of the concentrations of many species, during both day and night, for 10 years, from July 2002 to April 2012. MIPAS measurements allowed to study the atmosphere from the upper troposphere to the stratosphere and above, up to the thermosphere. The interest in these measurements goes beyond the end of the mission, as they can be used in long time series of data to determine changes in atmospheric composition and in our planet's climate. Furthermore, if the Changing-Atmosphere Infra-Red Tomography Explorer (CAIRT) mission, one of four candidates for Earth Explorer 11, will be selected, MIPAS data will constitute a benchmark for these measurements. CAIRT exploits indeed the heritage of MIPAS on ENVISAT, but allows to measure the composition of the atmosphere with unprecedented three-dimensional resolution being the first imaging Fourier Transform spectrometer sounding the limb of the atmosphere from space. For the last reanalysis of the whole MIPAS mission, a significant effort was made by the MIPAS Quality Working Group, supported by ESA, to improve both L1 [1] and L2 processors, as well as spectroscopy and Level 2 Initial Guess profiles [2], with the objectives of obtaining L2 products with increased accuracy, better temporal stability, and a larger number of retrieved species. The main improvements of L1 processor were related to the radiometric calibration and pointing. With these new processors a MIPAS full mission reprocessing has been recently performed ([1] and [3]). The quality of this final operational data set has been assessed with comprehensive validation studies including comparisons to ground-based in-situ and balloon-borne measurements. The dataset containing the new version 8 of both L1 and L2 products and covering the entire MIPAS operational lifetime period (2002-2012) is available at ESA Earth Online web site.This paper will focus on the lessons learnt, on the quality of the reprocessed data, on the remaining problems, and on further improvements that could improve the quality of both MIPAS L1 and L2 datasets.[1] Kleinert et al. Kleinert, A., Birk, M., Perron, G., and Wagner, G.: Level 1b error budget for MIPAS on ENVISAT, Atmos. Meas. Tech., 11, 5657-5672,https://doi.org/10.5194/amt-11-5657-2018, 2018 [2] Raspollini, P., Arnone, E., Barbara, F., Bianchini, M., Carli, B., Ceccherini, S., Chipperfield, M. P., Dehn, A., Della Fera, S., Dinelli, B. M., Dudhia, A., Flaud, J.-M., Gai, M., Kiefer, M., López-Puertas, M., Moore, D. P., Piro, A., Remedios, J. J., Ridolfi, M., Sembhi, H., Sgheri, L., and Zoppetti, N.: Level 2 processor and auxiliary data for ESA Version 8 final full mission analysis of MIPAS measurements on ENVISAT, Atmos. Meas. Tech. Discuss. [preprint], https://doi.org/10.5194/amt-2021-235, in review, 2021. [3] Dinelli, B. M., Raspollini, P., Gai, M., Sgheri, L., Ridolfi, M., Ceccherini, S., Barbara, F., Zoppetti, N., Castelli, E., Papandrea, E., Pettinari, P., Dehn, A., Dudhia, A., Kiefer, M., Piro, A., Flaud, J.-M., Lopez-Puertas, M., Moore, D., Remedios, J., and Bianchini, M.: The ESA MIPAS/ENVISAT Level2-v8 dataset: 10 years of measurements retrieved with ORM v8.22, Atmos. Meas. Tech. Discuss. [preprint], https://doi.org/10.5194/amt-2021-215, accepted, 2021.

High quality long-term data sets of altitude-resolved measurements of the atmospheric composition areimportant because they can be used both to study the evolu-tion of the atmosphere and as a benchmark for future mis-sions. For the final ESA reprocessing of MIPAS (MichelsonInterferometer for Passive Atmospheric Sounding) on ENVISAT (ENViromental SATellite) data, numerous improve-ments were implemented in the Level 2 (L2) processor Op-timised Retrieval Model (ORM) version 8.22 (V8) and itsauxiliary data. The implemented changes involve all aspects of the processing chain, from the modelling of the measure-ments with the handling of the horizontal inhomogeneitiesalong the line of sight to the use of the optimal estimationtechnique to retrieve the minor species, from a more sensitive approach to detecting the spectra affected by cloudsto a refined method for identifying low quality products. Improvements in the modelling of the measurements werealso obtained with an update of the used spectroscopic dataand of the databases providing the a priori knowledge ofthe atmosphere. The HITRAN_mipas_pf4.45 spectroscopic database was finalised with new spectroscopic data verifiedwith MIPAS measurements themselves, while recently measured cross-sections were used for the heavy molecules. TheLevel 2 Initial Guess (IG2) data set, containing the clima-tology used by the MIPAS L2 processor to generate the ini-tial guess and interfering species profiles when the retrieved profiles from previous scans are not available, was improved taking into account the diurnal variation of the profiles defined using climatologies from both measurements and models. Horizontal gradients were generated using the ECMWFERA-Interim data closest in time and space to the MIPASdata. Further improvements in the L2 V8 products derivedfrom the use of the L1b V8 products, which were upgraded to reduce the instrumental temporal drift and to handle theabrupt changes in the calibration gain. The improvements in-troduced into the ORM V8 L2 processor and its upgraded auxiliary data, together with the use of the L1b V8 products, lead to the generation of the MIPAS L2 V8 products, which are characterised by an increased accuracy, better temporal stability and a greater number of retrieved species.

The Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) measured the middle-infrared limb emission spectrum of the atmosphere from 2002 to 2012 on board ENVISAT, a polar-orbiting satellite. Recently, the European Space Agency (ESA) completed the final reprocessing of MIPAS measurements, using version 8 of the level 1 and level 2 processors, which include more accurate models, processing strategies, and auxiliary data. The list of retrieved gases has been extended, and it now includes a number of new species with weak emission features in the MIPAS spectral range. The new retrieved trace species include carbonyl chloride (COCl2), also called phosgene. Due to its toxicity, its use has been reduced over the years; however, it is still used by chemical industries for several applications. Besides its direct injection in the troposphere, stratospheric phosgene is mainly produced from the photolysis of CCl4, a molecule present in the atmosphere because of human activity. Since phosgene has a long stratospheric lifetime, it must be carefully monitored as it is involved in the ozone destruction cycles, especially over the winter polar regions.In this paper we exploit the ESA MIPAS version 8 data in order to discuss the phosgene distribution, variability, and trends in the middle and lower stratosphere and in the upper troposphere. The zonal averages show that phosgene volume mixing ratio is larger in the stratosphere, with a peak of 40 pptv (parts per trillion by volume) between 50 and 30 hPa at equatorial latitudes, while at middle and polar latitudes it varies from 10 to 25 pptv. A moderate seasonal variability is observed in polar regions, mostly between 80 and 50 hPa. The comparison of MIPAS-ENVISAT COCl2 v8 profiles with the ones retrieved from MIPAS balloon and ACE-FTS (Atmospheric Chemistry Experiment - Fourier Transform Spectrometer) measurements highlights a negative bias of about 2 pptv, mainly in polar and mid-latitude regions. Part of this bias is attributed to the fact that the ESA level 2 v8 processor uses an updated spectroscopic database. For the trend computation, a fixed pressure grid is used to interpolate the phosgene profiles, and, for each pressure level, VMR (volume mixing ratio) monthly averages are computed in pre-defined 10? wide latitude bins. Then, for each latitudinal bin and pressure level, a regression model has been fitted to the resulting time series in order to derive the atmospheric trends. We find that the phosgene trends are different in the two hemispheres. The analysis shows that the stratosphere of the Northern Hemisphere is characterized by a negative trend of about -7 pptv per decade, while in the Southern Hemisphere phosgene mixing ratios increase with a rate of the order of +4 pptv per decade. This behavior resembles the stratospheric trend of CCl4, which is the main stratospheric source of COCl2. In the upper troposphere a positive trend is found in both hemispheres.

The observations acquired during the full mission of the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) instrument, aboard the European Space Agency Environmental Satellite (Envisat), have been analysed with version 8.22 of the Optimised Retrieval Model (ORM), originally developed as the scientific prototype of the ESA level-2 processor for MIPAS observations. The results of the analyses have been included into the MI- PAS level-2 version 8 (level2-v8) database containing atmospheric fields of pressure, temperature, and volume mixing ratio (VMR) of MIPAS main targets H2 O, O3 , HNO3 , CH4 , N2 O, and NO2 , along with the minor gases CFC- 11, ClONO2 , N2 O5 , CFC-12, COF2 , CCl4 , CF4 , HCFC-22, C2 H2 , CH3 Cl, COCl2 , C2 H6 , OCS, and HDO. The database covers all the measurements acquired by MIPAS in the nominal measurement mode of the full resolution (FR) part of the mission (from July 2002 to March 2004) and all the observation modes of the optimised resolution (OR) part (from January 2005 to April 2012). The number of species included in the MIPAS level2-v8 dataset makes it of particular importance for the studies of stratospheric chemistry. The database is considered by ESA the final release of the MIPAS level-2 products.The ORM algorithm is operated at the vertical grid coincident to the tangent altitudes of the observations or to a subset of them, spanning (in the nominal mode) the alti- tude range from 6 to 68km in the FR phase and from 6 to 70 km in the OR period. In the latitude domain, FR profiles are spaced by about 4.7o, while the OR profiles are spaced by about 3.7o. For each retrieved species, the auxiliary data and the retrieval choices are described. Each product is characterised in terms of the retrieval error, spatial resolution, and "useful" vertical range in both phases of the MIPAS mission. These depend on the characteristics of the measurements (spectral and vertical resolution of the measurements), the retrieval choices (number of spectral points in- cluded in the analyses, number of altitudes included in the vertical retrieval grid), and the information content of the measurements for each trace species. For temperature, water vapour, ozone, and nitric acid, the number of degrees of freedom is significantly larger in the OR phase than in the FR one, mainly due to the finer vertical measurement grid. In the FR phase, some trace species are characterised by a smaller retrieval error with respect to the OR phase, mainly due to the larger number of spectral points used in the analyses, along with the reduced vertical resolution. The way of handling possible caveats (negative VMR, vertical grid representation) is discussed. The quality of the retrieved profiles is assessed through four criteria, two providing information on the successful convergence of the retrieval iterations, one on the capability of the retrieval to reproduce the measurements, and one on the presence of outliers. An easy way to identify and filter the problematic profiles with the informa- tion contained in the output files is provided. MIPAS level2- v8 data are available to the scientific community through the ESA portal (https://doi.org/10.5270/EN1-c8hgqx4).

MIPAS is a Fourier Transform spectrometer that measured the atmospheric limb emission spectra in the middle infrared on board the ENVISAT satellite. These measurements allowed the global monitoring of the three-dimensional (latitude, longitude and altitude) distribution of concentrations of many species, during both day and night, for 10 years, from July 2002 to April 2012. Being a limb sounding instrument, the focus of MIPAS measurements was the study of the atmosphere from the upper troposphere to the stratosphere and above, up to the mesosphere. The interest in these measurements goes beyond the end of the mission, as they can be used in long time series of data to determine changes in our planet's climate. To this purpose, it is therefore important to continue improving their quality. The quality of MIPAS L2 products depends on the quality of the L1 products, on the L2 model accuracy, on the quality of auxiliary data, particularly on spectroscopic data. For the last reanalysis of the whole MIPAS mission, a significant effort was made by the MIPAS Quality Working Group, supported by ESA, to improve both L1 and L2 processors, as well as spectroscopy, with the objectives of obtaining L2 products with increased accuracy, better temporal stability, and a larger number of retrieved species. Here we present the full mission dataset, including vertical profiles of 21 trace species plus temperature, obtained by applying the latest version of ESA L2 processor (ORM V8) to the MIPAS L1 data obtained with version 8 of the L1 processor. The impact of the improvements of both L1 and L2 processors on the quality of the L2 products is presented, as well as results of the validation against independent correlative measurements.

Riporta i principali risultati ottenuti nell'ambito del progetto: "Support to MIPAS Level 2 processor Verification and Validation - Phase F", Contratto ESA 4000112093/14/I-LG, cioe' la messa a punto del codice ORM_V8 da utilizzare per la rianalisi di livello 2 dell'intera missione di MIPAS/ENVISAT, il dataset processato, i test di verifica e di validazione dei prodotti di Livello 2 generati.

The Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) is a limb-viewing infrared Fourier transform spectrometer that operated from 2002 to 2012 onboard the ENVISAT satellite. The analysis of MIPAS measurements allows to study the temporal evolution of numerous species of interest for the study of the ozone in the stratosphere, pollutants and many green-house gases. The objective of the MIPAS Quality Working Group is to improve the quality of the MIPAS products through a fruitful collaboration among spectroscopists, Level 1, Level 2, and validation teams. A large effort has recently led to implement significant improvements in both ESA Level 1 and Level 2 processors, as well as in spectroscopic database and in some absorption cross-sections in order to improve the quality of the products. In addition to the products already present in the V7 dataset (temperature and the VMR of H2O, O3, HNO3, CH4, N2O, NO2, CFC-11, CFC-12, N2O5, ClONO2, HCFC-22, COF2, CF4, HCN and CCl4), the VMR of six additional species (OCS, CH3Cl, HDO, C2H2, C2H6, COCl2) will be provided in V8 dataset. In order to evaluate the impact of the changes in the products before full mission reprocessing, the analysis of the performances of the products of the modified L1 and L2 processors, as well as the auxiliary data, has been performed on a Diagnostic DataSet (DDS). The orbits of the DDS have been chosen in coincidence with correlative measurements for performing also a preliminary assessment of the accuracy of the products and to evaluate possible changes in the drift. With respect to V7 products, main improvements consist in a reduction of the temperature bias in the first part of the mission, a reduction of the discontinuities in CH4 and N2O time series due to daily gain upgrade, a better filtering of clouds and a better handling of horizontal inhomogeneities.The results of the assessment of the quality of MIPAS measurements will be shown, as well as the study of the temporal evolution and variability of all species. We will also investigate the spatial, seasonal, and interannual variations in the distribution of these species.

The Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) is a limb-viewing infrared Fourier transform spectrometer that operated from 2002 to 2012 on board the ENVISAT satellite. The fruitful collaboration among spectroscopists, Level 1, Level 2, and validation teams in the frame of the MIPAS Quality Working Group has recently led to the implementation of significant changes in both ESA Level 1 and Level 2 processors, as well as in the spectroscopic database and in some absorption cross-sections. In addition to the products already present in V7 dataset (temperature and the VMR of H2O, O3, HNO3, CH4, N2O, NO2, CFC-11, CFC-12, N2O5, ClONO2, HCFC-22, COF2, CF4, HCN and CCl4), the VMR of six additional species (OCS, CH3Cl, HDO, C2H2, C2H6, COCl2) will be provided in V8 dataset.Among the new species, methyl chloride (CH3Cl) is of great interest in stratospheric ozone chemistry since it is the most abundant chlorine-containing gas in the troposphere and, in contrast to other relatively long-lived ozone-depleting gases, it has both natural and anthropogenic sources, with the known emission being mainly natural (tropical plants, biomass burning, the ocean, salt marshes and fungi). Since it is not controlled under the Montreal Protocol, its importance is expected to increase in the coming decades as emission controls alter the relative contributions from natural and anthropogenic halogen sources.In this paper we present a preliminary assessment of the quality of the MIPAS CH3Cl data, in terms of precision, accuracy and vertical resolution, and we investigate the spatial and seasonal variations in the distribution of CH3Cl in the upper troposphere/lower stratosphere (UTLS).

The Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) is a limb-viewing infrared Fourier transform spectrometer that operated from 2002 to 2012 onboard the ENVISAT satellite. The maintenance and the upgrade of both L1 and L2 ESA processors are accomplished by the Quality Working Group, where a fruitful collaboration among Level 1, Level 2 and validation teams can be exploited. Recently both ESA L1 and L2 processors have been updated, as well as the spectroscopic database and some absorption cross-sections. In addition to the products already present in the current release (V7) of ESA MIPAS data (temperature and the VMR of H2O, O3, HNO3, CH4, N2O, NO2, CFC-11, CFC-12, N2O5, ClONO2, HCFC-22, COF2, CF4, HCN and CCl4), the VMR of six additional species (OCS, CH3Cl, HDO, C2H2, C2H6, COCl2) will be provided in V8 dataset. In preparation of V8 full mission reprocessing, three Diagnostic Datasets have been generated to check the performances of all L1, L2 processors and the new auxiliary data.The analysis of these Diagnostic Datasets and the comparison with previous full mission dataset V7 will be used to perform a first assessment of the quality of the new V8 products. In the paper special focus will be given to the new species.

MIPAS on ENVISAT performed almost continuous measurements of atmospheric composition for approximately 10 years, from June 2002 to April 2012. ESA processor, based on the algorithm ORM (Optimized Retrieval Model), originally designed for the Near Real Time analysis, is currently used for the reanalysis of the full MIPAS mission. Version 7 of the full mission data was released in 2016, but further improvements have been recently performed in ORM V8 to be used in next full mission reanalysis. For these latest releases (V7 and V8) L1 data corrected for reducing the instrumental drift are used.TheinstrumentaldriftisduetoMIPASphotometricdetectorsnonlinearitiesthatchangewithtimeduetothe ageing of the instrument. Numerous species are retrieved from MIPAS measurements. Among them, CCl4 has been recently studied. This species has received increasing interest due to the so called "mystery of CCl4", since it was found that its atmospheric concentration at the surface declines with a rate significantly smaller than its lifetime-limited rate. Indeed there is a discrepancy between the atmospheric observations and the estimated distribution based on the reported production and consumption. MIPAS products generated with Version 7 of the L2 ESA algorithm were used to estimate CCl4 distributions, its trend, and atmospheric lifetime in the upper troposphere / lower stratosphere (UTLS) region. The trends derived by these observations between 2002 and 2012 as a function of both latitude and altitude confirm the decline of atmospheric mixing ratios, in agreement with ground based observations. Stratospheric trend derived from the MIPAS data are non-uniform, with some positive trends even being found in the middle stratosphere, mainly at high altitudes in the Southern Hemisphere. The variability in stratospheric trends reflects the impact of variability in stratospheric transport on trace gases and their temporal evolution. In addition to CCl4, some preliminary results obtained with the latest version of the processor (V8), that performs the analysis of a larger number of species and takes into account horizontal inhomogeneities, will be shown.

The largest part of the Earth's atmosphere ozone is located in the stratosphere, forming the so-called ozone layer. This layer played a key role in the development of life on Earth and still protects the planet from the most Dangerous ultraviolet radiation. After the discovery of the high ozone depletion potential of some anthropogenic origin substances (e.g. chlorofluorocarbons), some limitations in the production of the major ozone-depleting substances (ODS) have been applied with the Montreal Protocol in 1987. The reduction of the ODS concentrations in the stratosphere started in the mid-1990s and, thereafter, the stratospheric ozone layer should have started its recovery. In the attempt to detect this recovery we use the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) measurements to estimate the stratospheric ozone trend in the mission period (July 2002 - April 2012). In particular, we use MIPAS products generated with Version 7 of the Level 2 (L2v7) algorithm operated by the European Space Agency. The L2v7 data are based on the MIPAS Level 1b radiances Version 7. These radiances are calculated with an improved radiometric calibration that exploits a time-dependent non-linearity correction scheme. After this correction the residual drift of the calibration error is smaller than 1% across the entire mission, thus allowing to determine accurate trend estimates.

Atmospheric emissions of carbon tetrachloride (CCl4) are regulated by the Montreal Protocol due to its role as a strong ozone-depleting substance. The molecule has been the subject of recent increased interest as a consequence of the so-called "mystery of CCl4", the discrepancy between atmospheric observations and reported production and consumption. Surface measurements of CCl4 atmospheric concentrations have declined at a rate almost 3 times lower than its lifetime-limited rate, suggesting persistent atmospheric emissions despite the ban. In this paper, we study CCl4 vertical and zonal distributions in the upper troposphere and lower stratosphere (including the photolytic loss region, 70-20 hPa), its trend, and its stratospheric lifetime using measurements from the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS), which operated onboard the ENVISAT satellite from 2002 to 2012. Specifically, we use the MIPAS data product generated with Version 7 of the Level 2 algorithm operated by the European Space Agency. The CCl4 zonal means show features typical of long-lived species of anthropogenic origin that are destroyed primarily in the stratosphere, with larger quantities in the troposphere and a monotonic decrease with increasing altitude in the stratosphere. MIPAS CCl4 measurements have been compared with independent measurements from other satellite and balloon-borne remote sounders, showing a good agreement between the different datasets. CCl4 trends are calculated as a function of both latitude and altitude. Negative trends of about -10 to -15 pptv decade-1 (-10 to -30 % decade-1) are found at all latitudes in the upper troposphere-lower stratosphere region, apart from a region in the southern midlatitudes between 50 and 10 hPa where the trend is positive with values around 5-10 pptv decade-1 (15-20 % decade-1). At the lowest altitudes sounded by MIPAS, we find trends consistent with those determined on the basis of long-term ground-based measurements (-10 to -13 pptv decade-1). For higher altitudes, the trend shows a pronounced asymmetry between the Northern and Southern hemispheres, and the magnitude of the decline rate increases with altitude. We use a simplified model assuming tracer-tracer linear correlations to determine CCl4 lifetime in the lower stratosphere. The calculation provides a global average lifetime of 47 (39-61) years, considering CFC-11 as the reference tracer. This value is consistent with the most recent literature result of 44 (36-58) years.

MIPAS on ENVISAT performed almost continuous and global measurements of atmospheric temperature and composition from June 2002 to April 2012. These data are very useful for understanding atmosphere climatology from the upper troposphere to the mesosphere, including trends in composition and variability, as a reference for middle atmosphere ozone and general circulation as well as improvement of tropospheric composition retrievals. The ESA Level 2 processor, based on the Optimized Retrieval Model (ORM), originally designed for the Near Real Time analysis and developed by an European Consortium led by IFAC, is currently improved and used for the reanalysis of the full MIPAS mission. The maintenance and the upgrade of the ESA processor are made in the frame of the MIPAS Quality Working Group, where a fruitful collaboration among Level 1, Level 2 and validation teams is exploited. This collaboration is essential to improve the accuracy of the products and their characterization. This paper is meant to describe the most recent upgrades in the MIPAS processor, in particular the full mission was recently reprocessed with L1 V7 and L2 V7 processors, containing significant improvements with respect to previous version 6, and further improvements are in preparation, that will be collected in version 8 of the ESA processor. The improvements include both L1 and L2 processors, as well as the auxiliary data. In the L1 processor the correction of the instrumental drift caused by the ageing of the detectors has been implemented in order to reduce the non negligible systematic error in the trend estimation. Furthermore, the measured daily gain instead of the weekly gain is now used for the radiometric calibration that allows to better take account for the discontinuities in the gain that occasionally occur in MIPAS band B. Improvements in the L2 processor include a different approach for retrieving atmospheric continuum, the use of an a posteriori regularization with altitude dependent constraint, a better approach for handling interfering species, a reduced bias in CFC-11, the handling of horizontal inhomogeneities and the use of ECMWF altitude/pressure relation to determine more accurate altitudes. Improvements in the auxiliary data consist in the use of microwindows with larger information content, an improved spectroscopic database and diurnally varying climatological dataset. Furthermore, additional species are provided in the new processors, leading to a total of 22 retrieved species by the L2 version 8 processor. Each of these changes has a different impact on the Level 2 products. The individual contributions, as well as the cumulative effects, will be evaluated with a comparison with previous versions of MIPAS products and corresponding results of validation. Improvements in the trend determination will also be evaluated, as well as the quality of the new retrieved species.

Carbon tetrachloride (CCl?) is a strong ozone-depleting atmospheric gas regulated by the Montreal protocol. Recently it received increasing interest because it was found that at the surface its atmospheric concentration declines with a rate almost three times smaller than its lifetime-limited rate. Indeed there is a discrepancy between atmospheric observations and the estimated distribution based on the reported production and consumption (the so called "mystery of CCl?"). We use for the first time the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) measurements to estimate CCl? distribution, its trend, and atmospheric lifetime in the upper troposphere / lower stratosphere (UTLS) region. In particular, here we use MIPAS product generated with Version 7 of the Level 2 algorithm operated by the European Space Agency. The CCl? zonal means show features typical of long-lived species of anthropogenic origin that are destroyed primarily in the stratosphere: larger amounts are found in the troposphere, monotonically decreasing with altitude. We calculate CCl? trends as a function of both latitude and altitude: negative trends are found at all latitudes in the UTLS, apart from a region in the Southern mid-latitudes between 50 and 10 hPa where the trend is slightly positive. At the lowest altitudes sounded by the MIPAS scan we find trend values consistent with those determined on the basis of long-term ground-based measurements. CCl? global average lifetime of 46(38 - 60) years has been estimated using the tracer-tracer linear correlations approach and the CFC-11 as the reference tracer. This estimated value is consistent with the most recent literature result of 44(36 - 58) years.

Atmospheric emissions of Carbon tetrachloride CCl4 are regulated by the Montreal Protocol due to its role as a strong ozone-depleting substance. The molecule has been the subject of recent increased interest as a consequence of the so called ``mystery of CCl4,'' the discrepancy between atmospheric observations and reported production and consumption. Surface measurements of CCl4 atmospheric concentrations have declined at a rate almost three times smaller than its lifetime-limited rate, suggesting persistent atmospheric emissions despite the ban. In this paper, we study CCl4 vertical and zonal distributions in the upper troposphere and lower stratosphere (including the photolytic loss region, 70-20 hPa), its trend, and its stratospheric lifetime using measurements from the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS), which operated onboard the ENVISAT satellite from 2002 to 2012. Specifically, we use the MIPAS data product generated with Version 7 of the Level 2 algorithm operated by the European Space Agency.The CCl4 zonal means show features typical of long-lived species of anthropogenic origin that are destroyed primarily in the stratosphere, with larger quantities in the troposphere and a monotonic decrease with increasing altitude in the stratosphere. In the troposphere, the largest concentrations are observed at the latitudes of major industrial countries (20/50°N). The good agreement we find between MIPAS CCl4 and independent measurements from other satellite and balloon-borne remote sounders proves the reliability of the MIPAS dataset.CCl4 trends are calculated as a function of both latitude and altitude. Negative trends are found at all latitudes in the upper-troposphere / lower-stratosphere region, apart from a region in the Southern mid-latitudes between 50 and 10 hPa where the trend is positive. At the lowest altitudes sounded by MIPAS, we find trends consistent with those determined on the basis of long-term ground-based measurements. For higher altitudes, the trend shows a pronounced asymmetry between Northern and Southern Hemispheres, and the magnitude of the decline rate increases with altitude. At 50 hPa the decline is about 30-35 %/decade, close to the lifetime-limited trend.We use a simplified model assuming tracer-tracer linear correlations to determine CCl4 lifetime in the lower stratosphere. The calculation provides a global average lifetime of 46(38-60) years considering CFC-11 as the reference tracer. This value is consistent with the most recent literature result of 44(36-58) years.

MIPAS on ENVISAT performed almost continuous measurements of atmospheric composition for approximately 10 years, from June 2002 to April 2012. ESA processor, based on the algorithm ORM (Optimized Retrieval Model), originally designed for the Near Real Time analysis and developed by an European Consortium led by IFAC, is currently used for the reanalysis of the full MIPAS mission. The maintenance and the upgrade of the ESA processor are made in the frame of the Quality Working Group, where a fruitful collaboration among Level 1, Level 2 and validation teams can be exploited. This collaboration is essential to pursue improvements in the accuracy of the products and their characterization. This paper is meant to describe the most recent upgrades in the ESA processor performed to improve the quality of ESA products. In particular, the full mission was recently reprocessed with L1 V7 and L2 V7 processors, containing significant improvements with respect to previous version V6, and further improvements are in preparation, that will be collected in version 8 of the ESA processor. Improvements involve both L1 and L2 processors, as well as the auxiliary data. Improvements in the L1 processor consist in a correction of the instrumental drift, improved spike detection algorithm and new Instrument Line Shape, as well as the use of measured daily gain instead of weekly gain. Improvements in the L2 processor include a different approach for retrieving atmospheric continuum, the use of an a posteriori regularization with altitude dependent constraint, a better approach for handling interfering species, a reduced bias in CFC-11, the handling of horizontal inhomogeneities and the use of ECMWF altitude/pressure relation for determining more accurate altitudes. Improvements in the auxiliary data consist in the use of microwindows with larger information content, new spectroscopic database and diurnally varying climatological dataset. Furthermore, with each new version additional species are provided, leading to 20 the number of retrieved species by the L2 V8 processor. Improvements in the V7 products will be revised on the light of the results of the validation with correlative measurements, and, by comparing the first new L2 V8 products with the L2 V7 ones, a preliminary assessment of the performance of the new V8 processor will be performed.